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The Ion Chromatography system seen here is one of the analytical
techniques used at the GCI to measure low indoor concentrations
of acetic acid and similar gases from construction and display
materials. Photo: James Druzik.
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To measure the capacity of adsorbents
for single and combinations of gases, permeation and diffusion
tubes are used to deliver set concentrations under controlled
conditions. Here, laboratory air is preconditioned, the flow
rates carefully measured, and adsorbents exposed for periods
of from 2 to 4 months. Photo: Jeffrey Levin.
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The packed gas tube on the right
contains pellets of adsorbent spaced between white, irregular
pieces of Teflon. The path of the gas flow is sufficiently mixed
that when coupled with a very long residence time all of the
pollutant has had time to react with the adsorbent. Photo: Jeffrey
Levin.
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In this set-up, finely powdered and
granular adsorbents are exposed to 2 ppm formic acid at 50%
RH for 12 weeks. Periodically samples are removed for monitoring
the progress of the exposure. Samples are analyzed using thermalgravimetry
(TG), differential thermal analysis, and evolved gas analysis
in one operation. Separately, total weight % carbon, nitrogen,
hydrogen, and sulfur are analyzed to support the TG analysis.
Photo: Jeffrey Levin.
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For a special type of material called a "chemisorbent,"
a known quantity of gas is passed through a bed of chemisorbent
until the pollutant breaks through the bed and can be measured
at the outlet. On the right is about 2 grams of purple-red Purafil.
On the left is the same material now brownish-black after reacting
with about 11 weight % acetic acid. In the middle, 14.5 weight
percent of formic acid has exhausted the potassium permanganate
(the brownish-black material) and then proceeded to react further
with the alumina substrate (the white efflorescence). Photo:
Jeffrey Levin.
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